Metals and Non-Metals - Part I


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There are about 90 elements, up to Uranium, that are found naturally. Another 20 elements, beyond Uranium, called trans-uranium elements, have been produced artificially in the laboratories by nuclear reactions. Two elements, Technetium (Tc) and Promethium (Pm) that occur below Uranium are unstable in nature. Elements can be classified by the physical and chemical properties that they display. We have discussed about classification of elements in earlier chapters.

The chemical behavior of all elements depends on their electronic configurations. It is the electrons that take part in chemical reactions and therefore their interactions are the main factors that determine the outcome of a chemical reaction. The periodic table of elements has been made on the basis of electronic configuration of elements alone.

Depending on the availability of “free” electrons, elements can be classified as metals and non-metals. Free electrons are unbound electrons, beyond closed shells. In metals, these unbound electrons are given off or donated during compound formation. In non-metals, there are no free electrons, instead there is a deficiency of electrons. While forming compounds, non-metals borrow electrons. Examples of metals are Sodium (Na), Potassium (K), Gold (Au). Examples of non-metals are Carbon (C ), Oxygen (O), Nitrogen (N), Chlorine (Cl). Metals are shown on the left-hand side and centre of the periodic table. Non-metals are placed on the right hand side of the periodic table. Chemically inert gases like Helium (He), Neon (Ne), Argon (Ar), Krypton (Kr) and Xenon (Xe) are included in the category of non-metals.

Some elements placed in between the metals and non-metals in the periodic table are called metalloids. Metalloids behave either like metals or like non-metals; their behavior depends on the environment that they are placed into. Metalloids are few in number. Examples of metalloids are Arsenic (As), Antimony (Sb), Germanium (Ge), etc. Thus metalloids form a bridge between strictly metal elements and strictly non-metal elements.

What we will study in this chapter :
1. Electronic configuration of metals and non-metals
2. Physical and chemical properties of metals
3. Reactivity series of metals
4. Physical and chemical properties of non-metals
5. Comparison between metals and non-metals
6. Metallurgy : extraction of ores and refining of ores
7. Study of some metals
8. Uses of metals
9. Compounds of metals and alloys
10. Study of some non-metals  

1. Electronic configuration of metals and non-metals
Metals are elements that give off “free” electrons. Metals generally have anywhere between 1 to 3 electrons excess of a closed shell. Non-metals on the other hand have similar number of electrons in deficit of the numbers required for a closed shell.

Table below gives electronic configuration of some metals.

Name of the element (symbol) Atomic number (Z) Total number of electrons Electronic Configuration

K      L      M      N

Sodium (Na) 11 11 2 8 1  
Aluminium (Al) 13 13 2 8 3  
Calcium (Ca) 20 20 2 8 8 2

Table below gives electronic configuration of some non-metals.

Name of the element (symbol) Atomic number (Z) Total number of electrons Electronic Configuration

K      L      M      N

Carbon (C) 6 6 2 4    
Oxygen (O) 8 8 2 6    
Chlorine (Cl) 17 17 2 8 7  

It is clear from these tables that to complete a given orbit, metals give off electrons and become positive ions. Non-metals accept electrons and become negative ions. Hydrogen (H) and Helium (He) are two light elements which are non-metallic in nature. Hydrogen lacks one electron to complete its one and only one shell. Helium has 2 electrons in its only orbit[1].

As discussed earlier in the chapter on Classification of Elements, the periodic table of elements has classified elements in different groups and periods. The groups and periods are made according to the electronic configuration of elements. The metals are placed on the left side and the centre of the periodic table. The non-metals are placed on the right side of the periodic table. Hydrogen is the only non-metal that is placed on the left-hand side of the periodic table. The reason for this is that the electronic configuration of H is 1s1, same as the Group I A elements or the alkali elements such as Na, and K. The middle portion of the periodic table consists of elements that are called transition metals elements. These elements are metallic in nature but not as metallic as alkali (Na, K, Cs etc)  or alkaline earth metals (Mg, Ca etc.)

[1] Although H and He are taken as non-metals, these elements show metallic properties at ultra low temperatures (close to absolute zero or 0 K).

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